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[1]张嬿妮,陈少康,康付如,等.含氢氧化铝RTV-2硅橡胶泡沫的阻燃抑烟性能研究[J].中国安全生产科学技术,2018,14(5):155-160.[doi:10.11731/j.issn.1673-193x.2018.05.023]
　ZHANG Yanni,CHEN Shaokang,KANG Furu,et al.Study on flame retardancy and smoke suppression performance of RTV-2 silicone rubber foam containing aluminum hydroxide[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2018,14(5):155-160.[doi:10.11731/j.issn.1673-193x.2018.05.023]
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含氢氧化铝RTV-2硅橡胶泡沫的阻燃抑烟性能研究
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《中国安全生产科学技术》[ISSN:1673-193X/CN:11-5335/TB]

卷:
14
期数:
2018年5期
页码:
155-160
栏目:
职业安全卫生管理与技术
出版日期:
2018-05-31

文章信息/Info

Title:
Study on flame retardancy and smoke suppression performance of RTV-2 silicone rubber foam containing aluminum hydroxide
文章编号:
1673-193X(2018)-05-0155-06
作者:
张嬿妮1; 2; 陈少康1; 2; 康付如1; 2; 刘志超1; 2; 邓军1; 2; 冯志超1; 2
（1.西安科技大学 安全科学与工程学院，陕西 西安 710054；2. 陕西省煤火防治重点实验室，陕西 西安 710054）
Author(s):
ZHANG Yanni1; 2;  CHEN Shaokang1; 2;  KANG Furu1; 2;  LIU Zhichao1; 2;  DENG Jun1; 2;  FENG Zhichao1; 2
(1.School of Safety Science and Engineering, Xi'an University of Science and Technology, Xi'an Shaanxi 710054, China;2.Shaanxi Key Laboratory of Prevention and Control of Coal Fire, Xi'an Shaanxi 710054, China)
关键词:
硅橡胶泡沫; 阻燃性能; 力学性能; 氢氧化铝
Keywords:
silicone rubber foam;  flame retardancy;  mechanical property;  aluminum hydroxide
分类号:
X928.7;TQ333.93
DOI:
10.11731/j.issn.1673-193x.2018.05.023
文献标志码:
A
摘要:
为研究氢氧化铝对RTV-2硅橡胶泡沫材料阻燃性能的影响，利用端乙烯基二甲基硅氧烷、气相法白炭黑、α, ω-二羟基聚二甲基硅氧烷、含氢硅油和氢氧化铝等原料制成硅橡胶泡沫材料，对其氧指数、烟密度、热稳定性和力学性能进行测试。研究结果表明：氢氧化铝的量从5%增加到25%时，硅橡胶泡沫阻燃性能增强，氧指数增加到34.1%；发烟量减少，最大烟密度和烟密度等级最多降低50.9%和52%；热稳定性提升，质量损失最少为25.65%；力学性能降低。综合考虑材料的阻燃抑烟性能和力学性能，添加量为15%时最佳。对15%的试样进行CONE测试，与原样相比，其燃烧过程的热释放速率下降了51%，FPI值提升到0.5，FGI值降低到1.09，能够有效提高阻燃抑烟性能。
Abstract:
In order to study the influence of aluminum hydroxide on the flame retardancy of RTV-2 silicone rubber foam, the material of silicone rubber foam was prepared by using the vinyl terminated dimethyl siloxane, fumed silica, α, ω-dihydroxy polydimethylsiloxane, hydrogen-containing silicone oil, aluminum hydroxide and other raw materials, then the oxygen index, smoke density, thermal stability and mechanical properties of the material were tested. The results showed that when the content of aluminum hydroxide increased from 5% to 25%, the flame retardancy of the silicone rubber foam strengthened, and the oxygen index increased to 34.1%. Meanwhile, the smoke generation decreased, and the maximum smoke density and smoke density level decreased by 50.9% and 52% at most, respectively. The thermal stability increased, the mass loss was 25.65% at least, and the mechanical properties decreased. Comprehensively considering the flame retardancy, smoke suppression performance and mechanical properties of the material, the optimal addition amount was 15%. The CONE tests were carried out on the sample with the addition amount of 15%, and compared with the original sample, the heat release rate during the combustion process reduced by 51%, the FPI value increased to 0.5, and the FGI value reduced to 1.09, which showed that it can improve the flame retardancy and smoke suppression performance effectively.

参考文献/References:

［1］张长生, 聂福德, 赵祺,等. 乙烯基硅油对纯化学发泡硅橡胶泡沫性能影响［J］. 化工新型材料, 2004, 32(8): 9-11. ZHANG Changsheng, NIE Fude, ZHAO qi, et al. Effect of vinyl silicone oil on properties of chemical-foaming silicone rubber［J］. New Chemical Materials, 2004, 32(8): 9-11.
［2］王作龄. 海绵橡胶用发泡剂与硫化体系［J］. 世界橡胶工业, 2008, 35(9):7-15. WANG Zuoling. Foamer and vulcanization system of sponge［J］. World Rubber Industry, 2008, 35(9):7-15.
［3］杨志国. 可瓷化阻燃耐火硅橡胶材料研究综述［J］. 当代化工, 2017, 46(8):1655-1658. YANG Zhiguo. Research progress of ceramifiable flame retardant silicone rubber materials［J］. Contemporary Chemical Industry, 2017, 46(8):1655-1658.
［4］李学锋, 陈绪煌. 氢氧化铝阻燃剂在高分子材料中的应用［J］. 中国塑料, 1999(6):80-85. LI Xuefeng, CHEN Xuhuang. Applications of Al(OH)3 fleme retardant in polymers［J］. China Plastics, 1999(6):80-85.
［5］毛华英, 蔡茴芳. 氢氧化铝的粒径对难燃输送带性能的影响［J］. 橡塑资源利用, 1990(1):4-5. MAO Huaying,CAI Huifang. Effect of aluminum hydroxide particle size on performance of flame-retardant conveyor belt［J］. Rubber and Plastic Resources Utilization, 1990(1):4-5.
［6］严玉, 段佳巍, 郑家青,等. 阻燃型 RTV 硅橡胶泡沫的制备［J］. 有机硅材料, 2014(3):153-156. YAN Yu, DUAN Jiawei, ZHENG Jiaqing, et al. Preparation of flame retardant RTV silicone rubber sponge［J］. Silicone Material, 2014(3):153-156.
［7］亢庆卫, 罗权焜. 氢氧化铝复合阻燃剂对热硫化硅橡胶性能的影响［J］. 有机硅材料, 2004, 18(6):1-4. KANG Qingwei, LUO Quankun. Effect of Al(OH)3 on the flame-retarded property of RTV silicone rubber［J］. Silicone Material, 2004, 18(6):1-4.
［8］WILLIAMS T C. Aminoorganopoly siloxane compositions with improved combustion resistance: US, US4701488［P］. 1987.
［9］郭建华, 曾幸荣, 李红强,等. 膨胀型阻燃剂对热硫化硅橡胶阻燃性能的影响［J］. 弹性体, 2011, 21(4):5-9. GUO Jianhua, ZENG Xinghong, LI Hongqiang, et al. Effect of intumescent flame retardants on flame-retarded properties of silicone rubber vulcanizates［J］. China Elastomerics, 2011, 21(4):5-9.
［10］RAMAZANI S A A, RAHIMI A, FROUNCHI M, et al. Investigation of flame retardancy and physical-mechanical properties of zinc borate and aluminum hydroxide propylene composites［J］. Materials & Design, 2008, 29(5):1051-1056.
［11］ZHUO J L, DONG J, JIAO C M, et al. Synergistic effects between red phosphorus and alumina trihydrate in flame retardant silicone rubber composites［J］. Plastics Rubber & Composites, 2013, 42(6):239-243.
［12］李兴建, 张宜恒, 孙道兴. 氢氧化镁/氢氧化铝/三聚氰胺磷酸盐协效无卤膨胀型阻燃硅橡胶的制备与性能研究［J］. 橡胶工业, 2013, 60(6):344-350. LI Xingjian, ZHANG Yiheng, SUN Daoxing. Preparation and properties of magnesium hydroxide/aluminum hydroxide/melamine phosphate filled flame retardant silicone rubber［J］. China Rubber Industry, 2013, 60(6):344-350.
［13］CAMINO G, LOMAKIN S M, LAZZARI M. Polydimethylsiloxane thermal degradation Part 1. Kinetic aspects［J］. Polymer, 2001, 42(6):2395-2402.
［14］黄东, 南海, 吴鹤. 氢氧化铝的阻燃性质与应用研究［J］. 材料开发与应用, 2004, 19(3):33-37. HANG Hong,NAN Hai, WU He. Flame retardancy property and application of Al(OH)3［J］. Development and Application of Materials, 2004, 19(3):33-37.
［15］谭珊. 低密度阻燃硅橡胶泡沫的制备与性能研究［D］. 青岛：青岛科技大学, 2017.
［16］梅庆波, 朱鹏, 刘惠平,等. 司班表面活性剂对氢氧化铝表面改性的研究［J］. 无机盐工业, 2015, 47(4):14-17. MEI Qingbo, ZHU Peng, LIU Huiping, et al. Research on surface modification of aluminum hydroxide by surfactants of Span［J］. Inorganic Chemicals Industry, 2015, 47(4):14-17.
［17］王胜杰, 李强. 硅橡胶/蒙脱土复合材料的制备,结构与性能［J］. 高分子学报, 1998, 1(2):149-153. WANG Shengjie, LI Qiang. Synthesis and Characterization of Silicone Rubber/Montmorillonite composites［J］. Acta Polymerica Sinica, 1998, 1(2):149-153.
［18］Wickstrm U, Gransson U. Full-scale/Bench-Scale correlations of wall and ceiling linings［J］. Fire & Materials, 1992, 16(1):15-22.
［19］MORGAN A B, BUNDY M. Cone calorimeter analysis of UL-94 V-rated plastics［J］. Fire & Materials, 2010, 31(4):257-283.
［20］SCHARTEL B, HULL T R. Development of fire-retarded materials—Interpretation of cone calorimeter data［J］. Fire & Materials, 2010, 31(5):327-354.
［21］卓金龙. 无卤阻燃室温硫化硅橡胶复合材料的制备及燃烧性能研究［D］. 青岛：青岛科技大学, 2014.

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备注/Memo

备注/Memo:
国家自然科学基金面上项目（51774232）；国家自然科学基金项目（51674191）；中国博士后科学基金项目（2016M592902XB）
更新日期/Last Update: 2018-06-19