|本期目录/Table of Contents|

[1]蒋慧灵,蒋治洪.氯化钠和二氧化硅对过硫酸铵热稳定性的影响[J].中国安全生产科学技术,2015,11(12):129-134.[doi:10.11731/j.issn.1673-193x.2015.12.020]
　JIANG Hui-ling,JIANG Zhi-hong.Influence of sodium chloride and silicon dioxide on thermal stability of ammonium persulfate[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2015,11(12):129-134.[doi:10.11731/j.issn.1673-193x.2015.12.020]
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氯化钠和二氧化硅对过硫酸铵热稳定性的影响
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《中国安全生产科学技术》[ISSN:1673-193X/CN:11-5335/TB]

卷:
11
期数:
2015年12期
页码:
129-134
栏目:
职业安全卫生管理与技术
出版日期:
2015-12-30

文章信息/Info

Title:
Influence of sodium chloride and silicon dioxide on thermal stability of ammonium persulfate
文章编号:
1673-193X(2015)-12-0129-06
作者:
蒋慧灵1; 蒋治洪2
（1. 中国人民武装警察部队学院 消防工程系，河北 廊坊 065000； 2. 中国人民武装警察部队学院 研究生部，河北 廊坊 065000）
Author(s):
JIANG Hui-ling1;  JIANG Zhi-hong2
(1. Department of Fire Protection Engineering, Chinese People's Armed Police Force Academy, Langfang Hebei 065000, China; 2. Department of Postgraduates, Chinese People's Armed Police Force Academy, Langfang Hebei 065000, China)
关键词:
安全工程; 热稳定性; 杂质; 热惰性因子; 绝热条件; 自加速分解温度
Keywords:
safety engineering;  thermal stability;  impurity;  thermal inertia factor;  adiabatic condition;  self-accelerating decomposition temperature
分类号:
X928.7
DOI:
10.11731/j.issn.1673-193x.2015.12.020
文献标志码:
A
摘要:
采用绝热加速量热仪（ARC）对分析纯过硫酸铵、含10%氯化钠杂质的过硫酸铵以及含10%二氧化硅杂质的过硫酸铵进行热分析实验，得到了实验过程中温度、温升速率和压力等数据，计算了3组样品的反应动力学参数，引入热惰性因子对实验数据进行修正，得到了3组样品在严格绝热条件下的热危险性参数，分析了3组样品的反应过程和热危险性。通过Semenov理论计算了3组样品的自加速分解温度（SADT）。结果表明，过硫酸铵加入氯化钠或二氧化硅杂质后，热危险性增大，自加速分解温度降低，更容易发生反应且反应更剧烈。
Abstract:
The thermal analysis experiments were conducted on pure ammonium persulfate, ammonium persulfate with 10% sodium chloride and ammonium persulfate with 10% silicon dioxide by using accelerating rate calorimeter(ARC), and the data of temperature, rise rate of temperature and pressure were obtained. The reaction kinetics parameters of three samples were calculated, and the thermal inertia factor was introduced to revise the experimental data. The thermal hazard parameters of three samples in absolute adiabatic conditions were obtained, and the reaction processes and thermal hazard of three samples were analyzed. The self-accelerating decomposition temperature(SADT) of three samples were calculated by Semenov theory. The results showed that: when ammonium persulfate is mixed with sodium chloride or silicon dioxide, the thermal hazard increases, the SADT becomes lower, and it is more possible to react and has a fierce reaction.

参考文献/References:

［1］陈迎春，经建生，田亮，等. 过硫酸铵的热不稳定性分析［J］. 消防科学与技术， 2005, 24(4): 408-411 CHEN Ying-chun, JING Jian-sheng, TIAN Liang, et al. Heat instability analysis of ammonium sulfate［J］. Fire Science and Technology, 2005, 24(4): 408-411
［2］李冠男，蒋慧灵，杨守生. 过硫酸铵的热稳定性研究［J］. 安全与环境学报， 2011 ,11(3): 191-195 LI Guan-nan, JIANG Hui-ling, YANG Shou-sheng. Study on the thermal stability of ammonium persulfate［J］. Journal of Safety and Environment, 2011 ,11(3): 191-195
［3］金满平，孙峰，张帆，等. 杂质对过硫酸铵热稳定性的影响［J］. 安全健康和环境，2014, 14(9): 35-39 JIN Man-ping, SUN Feng, ZHANG Fan, et al. The influence of impurities on thermal stability of ammonium sulfate［J］. Safety Health & Environment, 2014, 14(9): 35-39
［4］黄飞，王振刚，等. 过硫酸铵胶囊破解剂的自加速分解温度和自反应过程研究［J］. 安全与环境学报，2010, 10(3): 147-150 HUANG Fei, WANG Zhen-gang, et al. Study on the self-accelerating decomposition temperature and self reaction process of encapsulated ammonium persulfate gel breaker［J］. Journal of Safety and Environment, 2010, 10(3): 147-150
［5］张金梅. 过硫酸铵胶囊破胶剂的混储危险性研究［J］. 中国安全生产科学技术，2013, 9(7): 66-70 ZHANG Jin-mei. Study on mixed storage risk of encapsulated ammonium persulfate gel breaker［J］. Journal of Safety Science and Technology, 2013, 9(7): 66-70
［6］钱新明，刘丽，张杰. 绝热加速量热仪在化工生产热危险性评价中的应用［J］. 中国安全生产科学技术， 2005, 1(4): 13-18 QIAN Xin-ming, LIU Li, ZHANG Jie. Accelerating rate calorimeter and its application in the thermal hazard evaluation of chemical production［J］. Journal of Safety Science and Technology, 2005, 1(4): 13-18
［7］傅智敏. 绝热加速量热法在反应性物质热稳定性评价中的应用［D］. 北京：北京理工大学，2002
［8］冯长根，傅智敏，钱新明. 绝热方法评价热安定性的改进模型与应用［J］. 北京理工大学学报，2003, 23(1): 22-25 FENG Chang-gen, FU Zhi-min, QIAN Xin-ming. Improved models and applications of adiabatic method for evaluating the thermal stability of chemicals［J］. Transactions of Beijing Institute of Technology, 2003, 23(1): 22-25
［9］何洁. 有机过氧化物的热危险性分析［D］. 南京: 南京理工大学，2008
［10］孙占辉，王瑜，孙金华. 有机过氧化物的热自燃性小药量评价法［J］. 应用化学，2005,22(1):1-4 SUN Zhan-hui, WANG Yu, SUN Jin-hua. Evaluation of autoignition of organic peroxides with small sample mass［J］. Chinese Journal of Applied Chemistry, 2005,22(1):1-4
［11］Semenov, NN. Some problems in chemical Kinetics and Reactivity［M］. U.S.A.: Princeton University Press, 1959
［12］Roduit B., Folly P., Berger B., et al. Evaluation SADT by Advanced Kinetics based Simulation Approach［J］. Journal of Thermal Analysis and Calorimetry, 2008, 93(1): 153-161

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备注/Memo

备注/Memo:
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更新日期/Last Update: 2016-01-25