|本期目录/Table of Contents|

[1]谢卓衡,张刚,韩子忠,等.模拟火灾中柔性有机堵料的热解性质及烟气研究*[J].中国安全生产科学技术,2022,18(7):164-170.[doi:10.11731/j.issn.1673-193x.2022.07.024]
 XIE Zhuoheng,ZHANG Gang,HAN Zizhong,et al.Study on pyrolysis properties and smoke of flexible organic plugging material in simulated fire[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2022,18(7):164-170.[doi:10.11731/j.issn.1673-193x.2022.07.024]
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模拟火灾中柔性有机堵料的热解性质及烟气研究*
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《中国安全生产科学技术》[ISSN:1673-193X/CN:11-5335/TB]

卷:
18
期数:
2022年7期
页码:
164-170
栏目:
职业安全卫生管理与技术
出版日期:
2022-07-31

文章信息/Info

Title:
Study on pyrolysis properties and smoke of flexible organic plugging material in simulated fire
文章编号:
1673-193X(2022)-07-0164-07
作者:
谢卓衡张刚韩子忠辜振宁李婷徐爽李艳徐树英
(1.海南省消防救援总队,海南 海口 571100;
2.海南大学 海口市固废物资源利用及环境保护重点实验室,海南 海口 570228;
3.海南大学 土木建筑工程学院,海南 海口 570228)
Author(s):
XIE Zhuoheng ZHANG Gang HAN Zizhong GU Zhenning LI Ting XU Shuang LI Yan XU Shuying
(1.Hainan Fire and Rescue Brigade,Haikou Hainan 571100,China;
2.Key Laboratory of Solid Waste Resource Utilization and Environmental Protection,Hainan University,Haikou Hainan 570228,China;
3.College of Civil Engineering,Hainan University,Haikou Hainan 570228,China)
关键词:
柔性有机堵料热辐射烟气分析热重元素分析
Keywords:
flexible organic plugging material thermal radiation smoke analysis DTG-TG elemental analysis
分类号:
X932
DOI:
10.11731/j.issn.1673-193x.2022.07.024
文献标志码:
A
摘要:
为探究在高温下柔性有机堵料的热解特性及热解烟气成分,采用元素分析和热重(TG)分析测试方法,对2种柔性有机堵料的组成及热解性质进行对比研究,并通过烟箱和烟气分析仪模拟火灾中常见的热辐射环境,研究模拟火灾环境中2种柔性有机堵料有毒有害气体的释放情况及释放规律。研究结果表明:2种柔性有机堵料均有较好的耐火性能;在模拟火灾的热辐射环境中,2种柔性有机堵料均释放多种有毒有害气体,且大部分气体在受热辐射后10~75 min时间范围内释放,并主要集中在30~50 min时间范围内;2种柔性有机堵料样品所释放的气体组分种类大致相同但各组分含量有着较大的差异,可能与2种柔性有机堵料成分组成种类相似,但各组分含量比例不同有关。
Abstract:
In order to explore the pyrolysis characteristics and the pyrolytic smoke composition of flexible organic plugging materials at high temperature,the composition and pyrolysis properties of two kinds of flexible organic plugging materials were studied by the elemental analysis and thermogravimetric (TG) analysis methods.The common thermal radiation environment in fire was simulated by smoke box and smoke analyzer,and the release status and release law of toxic and harmful gases from two kinds of flexible organic plugging materials in simulated fire environment were studied.The results showed that both the two kinds of flexible organic plugging materials had good fire resistance.In the thermal radiation environment of simulated fire,both the two kinds of flexible organic plugging materials released a variety of toxic and harmful gases,and most of the gases released within the time range of 10~75 minutes after the thermal radiation and mainly within the time range of 30~50 minutes.In addition,the types of gas components released by the two kinds of flexible organic plugging materials were roughly the same,but the contents of each component were greatly different,which might be related to different content proportions of each component although the types of components of the two kinds of flexible organic plugging materials were similar.

参考文献/References:

[1]YI X,LEI C,DENG J,et al.Numerical simulation of fire smoke spread in a super high-rise building for different fire scenarios[J].Advances in Civil Engineering,2019,(1):1-11.
[2]CHENG J J,SUN S H.Investigation on the fire hazard of hybrid polymer materials based on the test of smoke toxicity[J].Journal of Thermal Analysis & Calorimetry,2019,135(4):2347-2357.
[3]STEFANIDOU M,ATHANASELIS S,SPILIOPOULOU C.Health impacts of fire smoke inhalation[J].Inhalation Toxicology,2008,20(8),761-766.
[4]KMITA A,BENKO A,ROCZNIAK A,et al.Pyrolysis of organic ester cured alkaline phenolic resin:identification of products[J].Journal of Analytical & Applied Pyrolysis,2018,129:6-12.
[5]HOFFMAN K,LORENZO A,BUTT C M,et al.Exposure to flame retardant chemicals and occurrence and severity of papillary thyroid cancer:a case-control study[J].Environment International,2017,107:235-242.
[6]XIN S,WEI G,WANG Y,et al.Thermochemical emission and transformation of chlorinated paraffins in inert and oxidizing atmospheres[J].Chemosphere,2017,185:899-906.
[7]XIN S,GAO W,WANG Y,et al.Identification of the released and transformed products during the thermal decomposition of a highly chlorinated paraffin[J].Environmental Science & Technology,2018,52(17):10153-10162.
[8]CHEN X,MA C,JIAO C.Synergistic effects between iron-graphene and melamine salt of pentaerythritol phosphate on flame retardant thermoplastic polyurethane[J].Polymers for Advanced Technologies,2016,27(11):1508-1516.
[9]WU Z,YANG L,ZHAN J,et al.Experimental study on polystyrene with intumescent flame retardants from different scale experiments[J].Fire & Materials,2016,40(1):18-26.
[10]LI L,YANG Y,LYU Y,et al.Porous calcite CaCO3 microspheres:preparation,characterization and release behavior as doxorubicin carrier[J].Colloids and Surfaces B:Biointerfaces,2019,186:110720.
[11]李婷,韩子忠,谢卓衡,等.柔性有机堵料热解特性及产物研究[J].消防科学与技术,2021,40(10):1513-1516.. LI Ting,HAN Zizhong,XIE Zhuoheng,et al.Study on the pyrolysis characteristics and products offlexible organic plugging material[J].Fire Science and Technology,2021,40(10):1513-1516.
[12]孔祥荣,马国儒,管旭东,等.傅里叶变换红外光谱法在火灾烟气分析测试中的应用[J].新材料产业,2016(1):50-53. KONG Xiangrong,MA Guoru,GUAN Xudong,et al.Application of Fourier transform infrared spectroscopy in fire smoke analysis and test[J].Advanced Materials Industry,2016(1):50-53.
[13]WOLTER N,BEBER V C,SANDINGE A,et al.Carbon,glass and basalt fiber reinforced polybenzoxazine:The effects of fiber reinforcement on mechanical,fire,smoke and toxicity properties\[J\],Polymers,2020,12(10):1-17.
[14]GEORLETTE P.Applications of halogen flame retardants-ScienceDirect[J].Fire Retardant Materials,2001:264-292.
[15]GUO T,LABELLE B,PETREAS M,et al.Mass spectrometric characterization of halogenated flame retardants[J].Rapid Communications in Mass Spectrometry,2013,27(13):1437-1449.
[16]赵杰,马骞,朱明学.一氧化碳和氢化氰在火灾烟雾中的毒性[J].中国药理学与毒理学杂志,2003(4):313. ZHAO Jie,MA Qian,ZHU Mingxue.Toxicity of carbon monoxide and cyanogen hydride in fire smoke[J].Chinese Journal of Pharmacology and Toxicology,2003(4):313.
[17]MOORE S J,HO I K,HUME A S.Severe hypoxia produced by concomitant intoxication with sublethal doses of carbon monoxide and cyanide[J].Toxicology & Applied Pharmacology,1991,109(3):412.
[18]DUQUESNE S,BRAS M L,BOURBIGOT S.Analysis of fire gases released from polyurethane and fire-retarded polyurethane coatings[J].Journal of Fire Sciences,2000,18(6):456-482.
[19]杨国强.丁基橡胶树脂硫化体系[J].天津橡胶,1996(4):4-7. YANG Guoqiang.Butyl rubber resin vulcanization system[J].Rubber & Plastics Resources Utilization,1996(4):4-7.
[20]GANN R G,BABRAUSKAS V,PEACOCK R D,et al.Fire conditions for smoke toxicity measurement[J].Fire and Materials,1994,18(3):193-199.
[21]黄恒栋,谯京旭.建筑火灾防治与救生方法[M].武汉:华中理工大学出版社,1996.

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备注/Memo

备注/Memo:
收稿日期: 2021-08-25
*基金项目: 海南省重点研发计划项目(ZDYF2019192);应急管理部消防救援局项目(2018XFCX31)
作者简介: 谢卓衡,本科,工程师,主要研究方向为封堵材料烟气分析及安全性评价。
通信作者: 徐树英,博士,教授,主要研究方向为封堵材料烟气分析及安全性评价。
更新日期/Last Update: 2022-08-10