|本期目录/Table of Contents|

[1]张青松,程相静,白伟.细水雾添加剂抑制锂电池火灾最佳浓度研究[J].中国安全生产科学技术,2018,14(5):43-50.[doi:10.11731/j.issn.1673-193x.2018.05.007]
　ZHANG Qingsong,CHENG Xiangjing,BAI Wei.Study on optimum concentration of additives in water mist for suppression of lithium battery fire[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2018,14(5):43-50.[doi:10.11731/j.issn.1673-193x.2018.05.007]
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细水雾添加剂抑制锂电池火灾最佳浓度研究
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《中国安全生产科学技术》[ISSN:1673-193X/CN:11-5335/TB]

卷:
14
期数:
2018年5期
页码:
43-50
栏目:
学术论著
出版日期:
2018-05-31

文章信息/Info

Title:
Study on optimum concentration of additives in water mist for suppression of lithium battery fire
文章编号:
1673-193X(2018)-05-0043-08
作者:
张青松; 程相静; 白伟
（中国民航大学 经济与管理学院，天津 300300）
Author(s):
ZHANG Qingsong;  CHENG Xiangjing;  BAI Wei
(School of Economics and Management, Civil Aviation University of China, Tianjin 300300, China)
关键词:
锂电池火灾; 细水雾; 添加剂; 添加浓度
Keywords:
lithium battery fire;  water mist;  additive;  addition concentration
分类号:
X949
DOI:
10.11731/j.issn.1673-193x.2018.05.007
文献标志码:
A
摘要:
为了研究针对锂电池火灾所适用的细水雾添加剂的最佳浓度，利用自主搭建平台进行7种不同浓度的常用添加剂抑制锂电池火灾实验，对温度变化趋势、最高温度以及最大冷却速率3个指标进行研究。结果表明：随着添加剂浓度逐渐增加，对锂电池火灾的抑制效果增加，至一个峰值后降低，峰值即为最佳添加浓度。对于物理添加剂而言，抑制效果较好的是季铵盐型碳氟阳离子氟表面活性剂，最佳添加浓度为0.16%；化学添加剂中效果较好是尿素，最佳添加浓度为0.32%。
Abstract:
In order to study the optimum concentration of additives in the water mist for the lithium battery fire, the experiments of suppressing the lithium battery fire by seven kinds of common additives with different concentrations were carried out by using the self-developed experimental platform, and three indexes including the variation trend of temperature, the maximum temperature and the maximum cooling rate were studied. The results showed that the suppression effect on the lithium battery fire increased with the increasing concentration of the additives, and then decreased after a peak value, which was the optimum addition concentration. For the physical additives, the additive with the better suppression effect was the quaternary ammonium fluorocarbon cationic fluorine surfactants, and the optimum addition concentration was 0.16%. For the chemical additives, the additive with the better suppression effect was the urea, and the optimum addition concentration was 0.32%.

参考文献/References:

［1］管道安. 18650型锂离子电池动力性能的研究［D］. 天津: 天津大学, 2005.
［2］FAA. Aviation cargo and passenger baggage incidents involving smoke, fire, extreme heat or explosion ［R］. FAA Office of Security and Hazardous Materials Safety, 2013.
［3］FAA. Risk in Transporting lithium batteries in cargo by aircraft．SAFO 10017［EB］.(2010-10-8) . http://www.faa.gov/other_visit/aviation_industry /airline＿operators/airline_safety/safo/all_safos/media/2010 /safo10017. pdf.
［4］张青松, 戚瀚鹏, 罗星娜，等. 电量影响下的锂离子电池热稳定性研究［J］. 消防科学与技术, 2015, 34(7):847-849. ZHANG Qingsong, QI Hangpeng, LUO Xingna, et al. A study on thermal stability of lithiumion battery during sir transportation against the influence of power ［J］. Fire Science and Technology, 2015, 34(7):847-849.
［5］FAA. Flammability assessment of bulk-packed, rechargeable lithium-ion cells in transport category aircraft［C］//DOT/FAA/AR-06/38, 2006.
［6］WANG Q S, SHAO G Z, DUAN Q L, et al. The efficiency of heptafluoropropane fire extinguishing agent on suppressing the lithium titanate battery Fire［J］. Fire Technology, 2016, 52(2):387-396.
［7］FAA. Extinguishment of lithium-ion and lithium-metal battery Fires［C］//DOT/FAA/TC-13/53, 2014
［8］刘江虹, 廖光煊, 范维澄，等. 细水雾灭火技术及其应用［J］ .火灾科学, 2001, 10(1):34-38. LIU Jianghong, LIAO Guangxuan, FAN Weicheng, et al. Introduction of water mist fire suppression technique ［J］. Fire Safety Science, 2001, 10(1):34-38.
［9］余明高, 李喜玲, 马科世，等. 含添加剂细水雾熄灭油池火的机理及实验［J］ .河南理工大学学报(自然科学版), 2006, 25(6):433-437. YU Minggao, LI Xiling, MA Keshi, et al. Experiments and mechanism of using spray mist with additives to extinguish kerosene pool fire［J］. Journal Of Henan Polytechnic University, 2006, 25(6):433-437.
［10］崔正心, 廖光煊. 细水雾抑制障碍物稳定火焰的实验研究［J］.火灾科学, 2001, 10(3):174-177. CUI Zhengxin, LIAO Guangxuan. Experimental investigation of water mist suppression of the flames stabilized by an obstruction ［J］. Fire Safety Science, 2001, 10(3):174-177.
［11］ZHU M X, ZHU S B, GONG J H, et al. Experimental study on fire and explosion characteristics of power lithium batteries with surfactant water mist［J］. Procedia Engineering, 2018（211）:1083-1090.
［12］WU B, LIAO G. Experimental study on fire extinguishing of water mist with a newly prepared multi-component additive ［J］. Procedia Engineering, 2013(62):317-323.
［13］CHAO M, ZHU S, JIA L, et al. Surfactant-containing water mist suppression pool fire experimental analysis ［J］. Procedia Engineering, 2014, 84(15):558-564.
［14］刘中麟, 范秀山. KHCO3作为细水雾添加剂灭火有效性研究［J］. 化工管理, 2014(24):32-33. LIU Zhonglin, FAN Xiushan. Study on the effectiveness of KHCO3 as a water mist additive for fire extinguishing ［J］. Chemical Management, 2014(24):32-33.
［15］丛北华, 毛涛, 廖光煊. 含NaCl添加剂细水雾对不同燃料池火灭火性能的实验研究［J］. 热科学与技术, 2004, 3(1): 65-70. CONG Beihua, MAO Tao, LIAO Guangxuan. Experimental investigation on fire suppression effectiveness for pool fires by water mist containing sodium chloride additive ［J］. Journal of Thermal Science and Technology, 2004, 3(1): 65-70.
［16］赵乘寿, 宫聪, 汪鹏，等. 含磷酸二氢铵细水雾灭火有效性研究［J］. 消防科学与技术, 2011, 30(9):822-824. ZHAO Chengshou, GONG Cong, WANG Peng, et al. Experimental study on fire suppression effectiveness of water mist with ammonium dehydrogenase phosphate, Fire Science and Technology, 2011, 30(9):822-824.
［17］陈玉红, 唐致远, 贺艳兵，等. 锂离子电池爆炸机理分析［J］. 电化学, 2006, 12(3):266-270. CHEN Yuhong, TANG Zhiyuan, HE Yanbing, et al. Research of explosion mechanism of lithium-ion battery ［J］. Electrochemical, 2006, 12(3):266-270.
［18］王青松, 孙金华, 姚晓林，等. 锂离子电池中的热效应［J］. 应用化学, 2006, 23(5):489-493. WANG Qingsong, SUN Jinhua, YAO Xiaolin, et al. Thermal behavior inside lithium-ion batteries ［J］. Chinese Journal of Applied Chemistry, 2006, 23(5):489-493.
［19］纪欢乐, 张青松, 吴斌斌，等. 新型细水雾添加剂成分对灭火性能影响研究［J］. 中国工程科学, 2012, 14(11):82-87. JI Huanle, ZHANG Qingsong, WU Binbin, et al. Research of the effect of the component proportion in the new water mist additive to extinguishing performance ［J］. Engineering Science, 2012, 14(11):82-87.
［20］LINTERIS G. Final report: effective non-toxic metallic fire suppressants ［R］. NIST Interagency/Internal Report (NISTIR)-6875, 2002.

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备注/Memo

备注/Memo:
中央高校基本科研业务费中国民航大学专项（3122017050）
更新日期/Last Update: 2018-06-19