|本期目录/Table of Contents|

[1]王凌云,唐敏康,梁辰.基于热风险理论对道化学评价中物质系数的研究[J].中国安全生产科学技术,2014,10(4):85-89.[doi:10.11731/j.issn.1673-193x.2014.04.015]
　WANG Ling yun,TANG Min kang,LIANG Chen.Study on material fatctor in Dow chemical evaluationbased on thermal risk theory[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2014,10(4):85-89.[doi:10.11731/j.issn.1673-193x.2014.04.015]
点击复制

基于热风险理论对道化学评价中物质系数的研究
分享到：

《中国安全生产科学技术》[ISSN:1673-193X/CN:11-5335/TB]

卷:
10
期数:
2014年4期
页码:
85-89
栏目:
职业安全卫生管理与技术
出版日期:
2014-04-28

文章信息/Info

Title:
Study on material fatctor in Dow chemical evaluationbased on thermal risk theory
作者:
王凌云;  唐敏康; 梁辰
（江西理工大学 资源与环境工程学院,江西赣州341000）
Author(s):
WANG Ling yun;  TANG Min kang;  LIANG Chen
(Jiangxi university of science and technology, Resources and environment engineering institute, Ganzhou Jiangxi 341000, China)
关键词:
安全科学技术基础学科;  道化学评价方法;  最大反应失效时间;  绝热温升
Keywords:
basic subject of safety science and technology;  Dow chemical evaluation method;  maximum response time to failure;  adiabatic temperature rise
分类号:
X937
DOI:
10.11731/j.issn.1673-193x.2014.04.015
文献标志码:
A
摘要:
随着本质安全研究的深入，道化学评价方法中物质系数MF的计算已不能准确描述反应物本身的热风险大小。在道化学评价方法中引入热风险概念，比较热危险性评价方法和道化学评价方法间相异点；以六甲基磷酰三胺工艺为研究对象，用DSC量热仪对反应物进行分析得出放热速率q、反应波峰峰值、单位质量的反应焓Hr，对采集的工艺参数用热力学理论外推法、基因贡献法得出活化能E、比热容CP并以此求出最大反应失效时间TMRad、绝热温升Qad、物质系数MF值以及工艺单元中物料量。得出最大反应失效时间与物质系数MF间具有相关性，道化学评价方法对因失效反应引发二次反应的热风险评估也适用。
Abstract:
With the development of safety research, material factor(MF value)of Dow chemical evaluation method can not accurately describe the size of thermal risk. The difference between thermal hazard evaluation method and Dow chemical evaluation method was analyzed by introducing thermal rick concept in Dow chemical evalution. DSC calorimeter was used to applysis the reactant so as to obtain heat release rate q, reaction wave peak and reaction enthalpy Hr. The thermodynamic theory extrapolation and group contribution method were applied to analyze the measurred process parameters, activation energy E and specific heat capacity CP were obtained, then the maximum response time to failure TMRad, adiabatic temperature rise Qad, material factor MF and the amount of material in the process unit were found out. It showed that the maximum response time to failure is related with MF, and Dow chemical evaluation method is useful for thermal risk assessment with secondary reaction caused by failure reaction.

参考文献/References:


[1］吴宗之.危险评价方法及其应用［M］. 北京：冶金工业出版社,2001：6.
[2］陈利平;间歇与半间歇反应热失控危险性评估方法［J］.化工学报,2008, 12（59）:2022 Chen Lipin; Batch and semibatch reactor thermal runaway risk assessment methods［J］. Chemical Engineering,2008, 12（59）:2022.
[3］Marco Eissen;The runaway scenario in the assessment of thermal safety: simple experimental access by means of the catalytic decomposition of H2O2［J］.Journal of Loss Prevention in the Process Industries, 2003(16):289296.
[4］宁绪成. 道化学评价法工艺单元相关危险系数取值探讨［J］.油气田地面工程, 2010,9(29):6062 NIN Xucheng. Dow chemical evaluation process unit values related risk factors discussed［J］. Oil and Gas Field Surface Engineering［J］,2010,9(29):6062.
[5］陈网桦.化工工艺的热安全风险评估与工艺设计［M］.北京：科学出版社，2009.
[6］王丽敏. 道化学火灾、爆炸危险指数法在1，3丁二烯安全性评价中的应用［J］.中国安全生产科学技术,2012,8(5):7075 WANG Limin. Dow chemical fire, explosion index of 1,3butadiene in the safety evaluation［J］. Journal of Safety Science and Technology, 2012,8(5):7075.
[7］胡荣祖.热分析动力［M］,北京:科学出版社,2001:8.
[8］马沛生.化工数据［M］,北京：中国石化出版社 2003:7.
[9］陈网桦.苯和甲苯硝化及磺化反应热危险性分级研究［J］. 中国安全科学学报,2010,20（5）:5052 CHEN Wanghua. Benzene and toluene nitration and sulfonation reaction heat hazard classification study ［J］.China Safety Science Journal, 2010, 20(5）:5052.
[10］刘秀玉. 化学放热系统热爆炸潜在危险性评价［J］, 中国安全科学学报,2006,16(12):7072 LIU Xiuyu. Chemical exothermic system thermal explosion hazard potential evaluation ［J］. China Safety Science Journal, 2006,16(12):7072.
[11］李丽霞， 周奕杉， 章晔， 等. 一种化学物质的热危险性研究［J］.中国安全生产科学技术,2012,8(10):1823 WANG Limin. Dow chemical fire, explosion index of 1,3butadiene in the safety evaluation［J］. Journal of Safety Science and Technology,2012,8(10):1823.

相似文献/References:

备注/Memo

备注/Memo:
-
更新日期/Last Update: 2014-04-28