|本期目录/Table of Contents|

[1]高波,施光明,姜华磊,等.尿素合成塔爆炸事故机理的研究[J].中国安全生产科学技术,2011,7(8):73-78.
 GAO Bo,SHI Guang-ming,JIANG Hua-lei.The research of urea reactor explosion mechanism[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2011,7(8):73-78.
点击复制

尿素合成塔爆炸事故机理的研究()
分享到:

《中国安全生产科学技术》[ISSN:1673-193X/CN:11-5335/TB]

卷:
7
期数:
2011年8期
页码:
73-78
栏目:
学术论著
出版日期:
2011-08-30

文章信息/Info

Title:
The research of urea reactor explosion mechanism
文章编号:
1673-193X(2011)-08-0073-06
作者:
高波; 施光明; 姜华磊;
四川大学化学工程学院;
Author(s):
GAO BoSHI Guang-mingJIANG Hua-lei
College of Chemical Engineering,Sichuan University,Chengdu 610065,China
关键词:
尿塔 爆炸 冲击波 机理 数值模拟
Keywords:
urea reactor explosion shock wave mechanism numerical simulation
分类号:
X933;TQ086
DOI:
-
文献标志码:
A
摘要:
尿素合成塔工艺条件复杂,体积庞大,内部物料状态复杂,需要在高温、高压下操作,国内外曾发生过几起著名的尿素合成塔爆炸事故,事故后果非常严重。工艺条件的复杂性加大了事故分析的难度,目前对事故原因众说纷纭。利用数值模拟软件,对尿素合成塔爆炸过程进行研究,对爆炸机理进行分析,对事故发生的原因进行探讨,为预防同类事故提供一定的依据。分析了顶部气相空间爆炸性混合体系的形成和爆炸过程,结合数值模拟得出关键点的压力变化和气相冲击波最终的压力,依据能量守恒推导出液相中冲击波的压力。利用数值模拟得出冲击波在液相中的传播速度和叠加的情况,综合反射、直接透射两部分冲击波进入液相的时间差,找到位于筒体底部的叠加点,冲击波在该处叠加造成筒体破裂,过热液体瞬间气化喷出,引发破坏更大的二次蒸汽大爆炸。
Abstract:
Urea reactor is operated at high temperature and high pressure.Several destructive explosions happened in and abroad.However,the complexity of process conditions increases the difficulty in the accident investigation.There is no agreement on the cause of the explosion.In the present paper,we simulated the explosion process by using the software FLUENT.The mechanism of explosion and the cause of the accident are analyzed,which provides some references to prevent similar accidents.Explosive mixture system of the top gas space and explosion process is analyzed.Combined with numerical simulation,the pressure change at key point and eventual pressure of gas phase shockwave were obtained,The liquid pressure wave was deduced according to energy conservation.The shock wave propagation velocity and superposition in the liquid ammonia were obtained by numerical simulation.Combined with the time difference of reflection,direct transmission liquid shock waves,the superimposition spot located at the bottom of cylindrical shell was found,which results in the tube body to destroy and overheating fluid ejected,even secondary explosion which is more intensive and destructive.

参考文献/References:

[1] T.Jojima. Urea reactor failure[J].Ammonia Plant Safety and Related Facilities,1979,21:111-119[2] 池树增.国外某厂尿素合成塔爆炸事故原因初探[J].中氮肥,2006,(2):10-13 CHI Shu-zeng. A brief reason analysis of urea synthesis tower explosion in a foreign factory[J]. M-Sized Nitrogenous Fertilizer Progre, 2006, (2):10-13.[3] 李化, 金长义, 黄卫星.化工装置连锁爆炸实例研究[J].中国安全生产科学技术,2008,4(1):99-103LI Hua , JIN Chang-yi , HUANG Wei-xing. Example research on chain explosion of chemical plant installations[J]. Journal of Safety Science and Technology, 2008,4(1):99-103[4] 李梦丽.层板包扎尿素合成塔爆炸和开裂原因及机理研究[D].济南:山东大学[硕士论文],2008[5] WANG Wei-qiang, LI Ai-ju, ZHU Yan-yong, YAO Xiao-jing, LIU Yan, CHEN Zhong-he. The explosion reason analysis of urea reactor of Pingyin[J],2009,16:972-986[6] 化工报社.一份有争议的事故报告的前前后后[EB].http://-www.cnfia.com.cn/files/zhcyw/showZHXW.asp?xuhao=7859, 2005-11-9[7] 吕延茂.尿素合成塔的化学爆炸分析[J].特种设备安全技术,2007,(6):26-32LV Yan-mao. Chemical explosion analysis of urea reactor [J]. Special equipment security technology, 2008, (6):34-37.[8] 沈华明.尿素合成的安全[J].化肥设计,2005,43(4):3-8SHEN Hua-ming. Safety of urea synthesis[J]. Chemical fertilizer design, 2005, 43(4):3-8[9] 杨柏森.关于尿素合成塔气相空间化学性爆炸问题的探讨[J].中氮肥,1992,(1):72-74 YANG Bo-seng. Discussed of chemical explosion in gas phase space of urea reactor[J].M-Sized Nitrogenous Fertilizer Progre,1992,(1):72~74[10] 郑津洋,匡继勇,徐平等.多层超高压容器爆破压力研究[J].化工机械,1994,21(5):271-277 ZHENG Jing-yang, KUANG Ji-yong, XU Ping, etal.Ulti-layer ultrahigh pressure container blasting pressure research[J]. Chemical machinery,1994,21(5):271-277[11] L.F. HENDERSON,Jia-Huan MA,Akira SAKURAI. Refraction of a shock wave at an air-water interface[J]. Fluid Dynamics Research,1990, 5: 337-350[12] 雷开卓,刘劲松,张群飞等.椭球反射罩在冲击波载荷下的动力学分析[J].机械科学与技术,2009,28(8):1068-1071 LEI Kai-zhuo, LIU Jin-song, ZHANG Qun-fei, etal. Dynamic Analysis of a Concave Ellipsoidal Reflector under Shock Wave[J]. Mechanical Science and Technology for Aerospace Engineering,2009,28(8):1068-1071[13] 北川彻三(黄九华译) .爆炸事故的分析[M].北京:化学工业出版社,1984[14] 胡德栋,王威强,吴俊飞等.平阴尿塔的物料和爆炸能量估算[J].山东大学学报(工学版),2008,38(3):46-50 HU De-dong, WANG Wei-qiang, WU Jun-fei, etal. Material component determination and explosion energy estimation ofthe Pingyin urea reactor[J].Journal of Shandong University (Engineering Science),2008,38(3):46-50

相似文献/References:

[1]张良,陶刚,张礼敬,等.PTG测定油脂与高压氧气的反应[J].中国安全生产科学技术,2011,7(11):63.
 ZHANG Liang,TAO Gang,ZHANG Li-jing,et al.Reaction of oil with high pressure oxygen measured by PTG[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2011,7(8):63.
[2]赵道亮.火灾与爆炸灾害控制课程建设与教学研究[J].中国安全生产科学技术,2011,7(11):82.
 ZHAO Dao-liang.Course construction and teaching research on control of fire and explosion calamity[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2011,7(8):82.
[3]韩力,刘鑫鹏,马金晶,等.基于CFD的半封闭空间内LNG泄漏后果研究[J].中国安全生产科学技术,2016,12(6):110.[doi:10.11731/j.issn.1673-193x.2016.06.020]
 HAN Li,LIU Xinpeng,MA Jinjing,et al.Study on consequence of LNG leakage in semi-confined space based on CFD[J].JOURNAL OF SAFETY SCIENCE AND TECHNOLOGY,2016,12(8):110.[doi:10.11731/j.issn.1673-193x.2016.06.020]

备注/Memo

备注/Memo:
收稿日期:2011-03-02
更新日期/Last Update: